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An in situ intercomparison exercise on passive samplers for monitoring metals, polycyclic aromatic hydrocarbons and pesticides in surface waters ArchiMer
Miege, C.; Mazzella, N.; Schiavone, S.; Dabrin, A.; Berho, C.; Ghestem, J. -p.; Gonzalez, C.; Gonzalez, Jean-louis; Lalere, B.; Lardy-fontan, S.; Lepot, B.; Munaron, Dominique; Tixier, Celine; Togola, A.; Coquery, M..
Tipo: Text Palavras-chave: Intercomparison exercise; Marine Strategy Framework Directive (MSFD); Metal; Passive sampling; Pesticide; Polar organic chemical integrative sampler (POCIS); Polycyclic aromatic hydrocarbon (PAH); Priority chemical; Surface water; Water Framework Directive (WFD).
Ano: 2012 URL: http://archimer.ifremer.fr/doc/00077/18853/16597.pdf
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Investigation of the matrix effects on a HPLC-ESI-MS/MS method and application for monitoring triazine, phenylurea and chloroacetanilide concentrations in fresh and estuarine waters ArchiMer
Mazzella, N.; Delmas, F.; Delest, B.; Mechin, B.; Madigou, C.; Allenou, Jean-pierre; Gabellec, Raoul; Caquet, Th..
In this work, the effects of matrix interferences on the analytical performance of a new multiresidue method based on off-line solid phase extraction followed by reversed-phase liquid chromatographic separation and electrospray triple quadrupole mass spectrometric detection were investigated. This technique allows the simultaneous determination of 30 triazines, phenylureas and chloroacetanilides, extracted from freshwaters, in 40 minutes. Quantifications were performed with the use of appropriate internal standards (i.e. atrazine D5, diuron D6 and metolachlor D6). The limits of quantification were from 1 to 32 ng L-1 for the triazines, from 5 to 59 ng L-1 for the phenylureas and from 13 to 54 ng L-1 for the chloroacetanilides. The matrix effects were...
Tipo: Text Palavras-chave: River estuarine interface; Natural water quality; Herbicides; Matrix effects; Multiresidue method; HPLC ESI MS/MS.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6092.pdf
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Risk assessment of herbicides and booster biocides along estuarine continuums in the Bay of Vilaine area (Brittany, France) ArchiMer
Caquet, Th.; Roucaute, M.; Mazzella, N.; Delmas, F.; Madigou, C.; Farcy, E.; Burgeot, Thierry; Allenou, Jean-pierre; Gabellec, Raoul.
A 2-year study was implemented to characterize the contamination of estuarine continuums in the Bay of Vilaine area (NW Atlantic Coast, Southern Brittany, France) by 30 pesticide and biocide active substances and metabolites. Among these, 11 triazines (ametryn, atrazine, desethylatrazine, desethylterbuthylazine, desisopropyl atrazine, Irgarol 1051, prometryn, propazine, simazine, terbuthylazine, and terbutryn), 10 phenylureas (chlortoluron, diuron, 1-(3,4-dichlorophenyl)-3-methylurea, fenuron, isoproturon, 1-(4-isopropylphenyl)-3-methylurea, 1-(4-isopropylphenyl)-urea, linuron, metoxuron, and monuron), and 4 chloroacetanilides (acetochlor, alachlor, metolachlor, and metazachlor) were detected at least once. The objectives were to assess the corresponding...
Tipo: Text Palavras-chave: Estuary; Herbicides; Booster biocides; Species sensitivity distribution; Risk quotient; AtlanticCoast.
Ano: 2013 URL: http://archimer.ifremer.fr/doc/00124/23571/22554.pdf
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